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Extra info for Chemoresponsive Materials
Weak electrolytes were observed to increase swelling kinetics substantially compared to strong electrolytes, which was attributed to the ease of ion transport through the membranes. Initially rubbery disks, on the other hand, did not exhibit these biphasic swelling fronts. Instead, they had monophasic but still non-Fickian sorption of the solvent. 38 The glucose bonded reversibly to the phenylboronic groups, imparting a charge to the boron atom. This charge induced swelling in the system similar to the cationic hydrogels.
Venturi, Chem. Soc. , 2006, 35, 1135. 08:13:55. 1039/9781782622420-00010 CHAPTER 2 Intelligent, Responsive and Theranostic Hydrogel Systems for Controlled Delivery of Therapeutics STEVE R. MAREK,a MARTIN L. GRAN,a NICHOLAS A. 1. Under the correct environmental conditions, these materials can imbibe significant amounts of water, often over two orders of magnitude more water than polymer by weight. 1 These properties help make RSC Smart Materials No. org 10 View Online 08:13:55. 1 11 Schematic of a polymeric hydrogel network.
1039/9781782622420-00001 References 1. (a) M. Wun-Fogle, Materials for Smart Systems, Cambridge University Press, 2014; (b) M. R. Aguilar and J. S. Roman, Smart Polymers and their Applications, Woodhead Publishing, 2014; (c) Q. Li, Intelligent StimuliResponsive Material, Wiley, 2013; (d) Handbook of Stimuli-Responsive Materials, ed. M. H. Urban, Wiley-VCH, Weinheim, 2011; (e) Intelligent Materials, ed. M. -J. Schneider, Royal Society of Chemistry, Cambridge, UK, 2007. 2. Recent reviews: (a) L. D.